Mars' atmosphere :
The weather on Mars
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A new study by researchers including those at the University of Tokyo revealed that atmospheric gravity waves play a crucial role in driving latitudinal air currents on Mars, particularly at high altitudes. The findings, based on long-term atmospheric data, offer a fresh perspective on the behaviours of Mars’ middle atmosphere, highlighting fundamental differences from Earth’s. The study applied methods developed to explore Earth’s atmosphere to quantitatively estimate the influence of gravity waves on Mars’ planetary circulation. According to ESA, Mars' atmosphere is composed of 95.32% carbon dioxide, 2.7% nitrogen, 1.6% argon and 0.13% oxygen. The atmospheric pressure at the surface is 6.35 mbar which is over 100 times less than Earth's. Humans therefore cannot breathe Martian air. The thermal impact of dust storms on Mars is significant, and is thought to play a similar role to that of water vapour in Earth’s atmosphere. For crewed Mars exploration efforts, we need to find a way to generate oxygen from the thin, carbon dioxide atmosphere and an experiment carried out on NASA's Perseverance rover has demonstrated it is possible. The rover used its MOXIE (short for "Mars Oxygen In-Situ Resource Utilization Experiment") to successfully convert carbon dioxide to oxygen on Mars. "MOXIE has more work to do, but the results from this technology demonstration are full of promise as we move toward our goal of one day seeing humans on Mars." Jim Reuter, associate administrator of NASA's Space Technology Mission Directorate, said.
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Despite it being a very cold planet, Mars is quite a hot topic these days. With human visitation seemingly on the horizon, it will pay to know more about the conditions there so all involved can plan and prepare accordingly. Something that has become possible to explore in detail in recent years is a range of Martian atmospheric phenomena. Naturally, a lot of the methods used for this originate from the study of our own atmosphere, and thanks to this, we can see how things on Mars differ greatly and what the implications of this might be. Mars' atmosphere is over 100 times thinner than Earth's and is primarily composed of carbon dioxide, nitrogen and argon gases. Oxidized dust particles kicked up from the Martian surface fill the atmosphere turning Mars' skies a rusty tan colour, according to NASA. Water exists on Mars but the atmosphere is too thin for it to last long on the surface in a liquid state. Instead, water on Mars is found below the surface of the polar regions as water-ice and also as seasonal briny water flows down hillsides and crater walls. Despite Mars' thin atmosphere, the Red Planet still exhibits a dynamic climate and extreme weather events including impressive dust storms and even snow! But Mars hasn't always been this way. NASA's MAVEN mission scientists reported that Mars once had a thick atmosphere that could have supported surface liquid water on the surface for extended periods of time.
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“On Earth, large-scale atmospheric waves caused by the planet’s rotation, known as Rossby waves, are the primary influence on the way air circulates in the stratosphere, or the lower part of the middle atmosphere. But study shows that on Mars, gravity waves (GWs) have a dominant effect at the mid and high latitudes of the middle atmosphere,” said Professor Kaoru Sato from the Department of Earth and Planetary Science. “Rossby waves are large-scale atmospheric waves, or resolved waves, whereas GWs are unresolved waves, meaning they are too fine to be directly measured or modelled and must be estimated by more indirect means.” Close up image of the surface of Mars shows white specks of salt deposits and numerous craters. Image from NASA's Mars Reconnaissance Orbiter shows the Bosporos Planum plain on the Red Planet. The white specks are salt deposits found within a dry channel, a clue to its watery past. Early in its history Mars had a thick enough atmosphere for water to run on its surface. According to NASA, some surface features suggest that Mars experienced huge floods about 3.5 billion years ago. Orbital pictures show vast river plains and possible ocean boundaries, while several Mars rovers have found evidence of water-soaked rocks on the surface (such as hematite or clay). However, for reasons that are still poorly understood, the Martian atmosphere thinned. Mars is much colder than Earth due to the thin atmosphere and the fact it is farther from the sun. The average temperature on Mars is about minus 80 degrees Fahrenheit (minus 60 degrees Celsius), although it can vary from minus 195 F (minus 125 C) near the poles during the winter to as much as a comfortable 70 F (20 C) at midday near the equator. Like Earth, Mars has four seasons but due to the Red Planet's eccentric orbit, the length of each season varies more than on Earth. A Year on Mars is almost twice as long as one on Earth. Following is the length of seasons on Mars and Earth according to NASA Science:-
Season (Northern Hemisphere) Length of Martian season (sols) Length of Earth season (days)
Spring 194 93
Summer 178 93
Autumn 142 90
Winter 154 89
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Not to be confused with gravitational waves from massive stellar bodies, GWs are an atmospheric phenomenon when a packet of air rises and falls due to variations in buoyancy. This oscillating motion is what gives rise to GWs. Due to the small-scale nature of them and the limitations of observational data, researchers have previously found it challenging to quantify their significance in the Martian atmosphere. So research team turned to the Ensemble Mars Atmosphere Reanalysis System (EMARS) dataset, produced by a range of space-based observations over many years, to analyse seasonal variations up there. “We found something interesting, that GWs facilitate the rapid vertical transfer of angular momentum, significantly influencing the meridional, or north-south, in the middle atmosphere circulations on Mars,” said graduate student Anzu Asumi. “It’s interesting because it more closely resembles the behaviour seen in Earth’s mesosphere rather than in our stratosphere. This suggests existing Martian atmospheric circulation models may need to be refined to better incorporate these wave effects, potentially improving future climate and weather simulations.”
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Mars' ice caps, made of water ice and carbon dioxide, shrink and grow in response to the seasons. These seasonal changes to the ice caps affect Mars' atmosphere, which responds as one large interconnected system, according to ESA. "The lower and middle levels of Mars' atmosphere appear to be coupled to the upper levels: there's a clear link between them throughout the martian year," says Beatriz Sánchez-Cano, a planetary scientist at the University of Leicester, UK. "Each winter, up to a third of the mass in Mars' atmosphere condenses to form an icy layer at each of the planet's poles. Every spring, some of the mass within these caps sublimates to re-join the atmosphere, and the caps visibly shrink as a result," ESA stated. Giant dust devils routinely kick up the oxidized iron dust that covers Mars' surface. Dust is also a permanent part of the atmosphere, with higher amounts of it in the northern fall and winter, and lower amounts in the northern spring and summer. The dust storms of Mars are the largest in the solar system, capable of blanketing the entire planet and lasting for months. These usually take place in the spring or summer. The research also underscores the importance of planetary comparisons in atmospheric science. Mars’ similarity to Earth in terms of rotational speed and axial tilt makes it an ideal test case for studying planetary weather systems. At the same time, its distinct characteristics, such as a thin carbon dioxide-rich atmosphere and pronounced seasonal variations, offer insights into alien atmospheres. By analysing these differences, researchers can improve their understanding of fundamental atmospheric dynamics, which may ultimately contribute to better climate models for Earth too.
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These dust storms can play havoc with Mars exploration missions and can even ground flights (yes Earth isn't the only planet where flights can be delayed due to poor weather!). NASA's Ingenuity Mars helicopter was due to make its 19th flight on the Red Planet on 5 Jan, 2022, when a dust storm near Jazero Crater had other plans. "Most notable was a sharp drop in air density, about a 7% deviation below what was observed pre-dust storm," Jonathan Bapst and Michael Mischna, of Ingenuity's weather/environment team, said. "This observed decrease would have put density below the lower threshold of safe flight and would have imparted undue risk to the spacecraft. We also observed the effect of dust in the amount of sunlight absorbed by Ingenuity's solar array, which fell well below normal 'clear sky' levels, a drop of about 18%." Over a month passed until Ingenuity was clear to fly again, finally acing its 19th flight on 8 Feb, 2022. “Looking ahead, we plan to investigate the impact of Martian dust storms on atmospheric circulation. So far, our analysis has focused on years without major dust storms,” said Sato. “However, these storms dramatically alter atmospheric conditions, and we suspect they may intensify the role of GWs in circulation. Our research lays the groundwork for forecasting Martian weather, which will be essential for ensuring the success of future Mars missions.”
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One theory as to why dust storms can grow so big on Mars starts with airborne dust particles absorbing sunlight, warming the Martian atmosphere in their vicinity. Warm pockets of air flow toward colder regions, generating winds. Strong winds lift more dust off the ground, which in turn heats the atmosphere, raising more wind and kicking up more dust. An earlier study further suggested that the momentum of Mars, which is affected by other planets, generates planet-circling dust storms when that momentum is at its greatest during the early part of the dust storm season. At times, it even snows on Mars. The Martian snowflakes, made of carbon dioxide rather than water, are thought to be very small particles that create a fog effect rather than appearing as falling snow. The north and south polar regions of Mars are capped by ice, much of it made from carbon dioxide, not water. Mars' early atmosphere was very different from the one we see today. Future studies will examine how these storms lead to significant shifts in global atmospheric patterns. With these advancements, the prospect of accurately predicting atmospheric conditions on Mars moves one step closer to reality. At some point in Mars' history, the Red Planet lost much of its atmosphere, transforming it from a warm wet world to the cold arid plains we see today, said ESA.
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The atmosphere of Mars changes over the course of a day because the ground gets extremely cold at night on Mars, down to around minus 160°C. At such cold temperatures, both major and minor constituents of the atmosphere might either condense (snow, frost) or just stick to the soil grains a lot more than they do at warmer temperatures. Because of differing condensation temperatures and "stickiness", the composition can change significantly with the temperature. During the day, the gases are released from the soil at varying rates as the ground warms, until the next night. It stands to reason that similar processes happen seasonally, as the water (H2O) and carbon dioxide (CO2) condense as frost and snow at the winter pole in large quantities while sublimating (evaporating directly from solid to gas) at the summer pole. It gets complicated because it can take quite a while for gas released at one pole to reach the other. Many species may be more sticky to soil grains than to ice of the same material, so for those chemicals, the diurnal change could be more significant than the seasonal change. The leading theory is that Mars' light gravity, coupled with its lack of global magnetic field, left the atmosphere vulnerable to pressure from the solar wind, the constant stream of particles coming from the sun. Over millions of years, the sun's pressure stripped the lighter molecules from the atmosphere, thinning it out. This process is being investigated by NASA's MAVEN (Mars Atmosphere and Volatile Evolution) mission. Other researchers hypothesize that perhaps a giant impact by a small body would have stripped the atmosphere away. The seasonal variation changes the global air pressure on Mars and changes which gases are in the air. On Mars, the air pressure can change globally by ±8%, depending on the season. The result is that there's no specific place, time of day, or season that fully represents THE composition of Mars' atmosphere. Finally, sunlight drives atmospheric chemistry by way of solar ultraviolet light breaking down CO2 and H2O molecules which are then free to react in new ways. As a result, the changing pressure and abundance of H2O and CO2 changes the abundance of carbon monoxide (CO), oxygen (O2), ozone (O3) and other trace species.
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Mars once was a more Earth-like planet, but it was the ancient Earth that it resembled, a planet with a CO2-rich atmosphere and no free oxygen, with extensive oceans that may have been frozen-over much of the time. We don't know for certain what chemicals were in the atmosphere of Earth besides CO2, N2 and H2O prior to the rise of widespread oxygen-producing photosynthesis which radically altered Earth's atmosphere. There could have been gases like methane (CH4) and ammonia (NH3), sulphur-bearing gases, and other gases which are not common today. We don't see those gases in Mars' atmosphere today, either, but possibly they were there in the past. The Sun has also been slowly increasing in luminosity, so that Mars and Earth of a few billion years ago had less sunlight to warm them, but more CO2 in the atmosphere to hold in the heat. Mars of a few billion years ago probably had exposed lakes and oceans, and probably had rain. Given how much uncertainty there is about how Earth's atmosphere may have been different when it was a younger and "less Earth-like" planet, it is awfully hard to make an educated guess as to what Mars' ancient atmosphere may have been like. Earth is particularly challenging because there has been constant chemistry and weathering as well as plate tectonics remaking the planet's surface over billions of years, minerals reacting with the atmosphere and sinking to the bottom of the oceans, then buried by tectonics. As we continue to gather new information about Mars, it may end up being our best guide to what Earth once was like, because the water chemistry on Mars, and plate tectonics, turned off a long time ago, leaving the rocks of that time intact for us to examine.
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The most obvious reason to think that Mars once had a much more dense atmosphere is that there are clear signs all over Mars of erosion by water in processes that occur on Earth but could not occur on Mars as it is today. There are river channels, eroded valleys, rocks worn into round river cobbles and dumped at the end of valleys, consistent with the way that rivers deposit rocks. More has changed than just the amount of water. Under current conditions, a puddle of liquid water at the surface would quickly evaporate, or freeze and then sublimate, because of the extremely low air pressure. For water to have once persisted long enough to flow in large quantities and to pool, the air pressure had to be much greater. From the surface, rovers have detected salt minerals layered in patterns that are consistent with the way that salty water forms lakes on Earth which evaporate over long periods of time in places like the Great Salt Lake or the Dead Sea, and in fully dried lakes such as salt flats in the American West, in Africa and numerous other places. From orbit, we have observed "bathtub rings" in large depressions in the surface and detected minerals which can only form when materials dissolve in water and have time to react with each other and accumulate in large quantities. What we lack is a good estimate of how much more dense the atmosphere once was. An important clue is in the isotopes of atmospheric gas atoms. Atoms in gases exist in different versions, called isotopes, that each have the same number of protons and electrons, but different numbers of neutrons in the nucleus. There are two stable versions of carbon, and three stable versions of oxygen.
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The ratio that we measure now between the abundance of stable isotopes depends on the original ratio when the planet formed, and then how it changed over time as heavy or light isotopes (more or fewer neutrons) were removed from the atmosphere by chemistry to form solids, or escaped to space. Hydrogen, nitrogen, and argon atoms are all enriched in heavy isotopes, consistent with losing a lot of gas to space, which removes the light isotopes faster than the heavy ones. Carbon and oxygen, which make the main atmospheric gas, carbon dioxide (CO2), are much more confusing. We need an estimate of what the isotope ratios actually are today, what they once were in the deep past, and how quickly each kind of isotope is lost from the atmosphere. With those things, we can estimate how much atmosphere has been lost and thus estimate how much atmosphere Mars once had. It will be a slow and messy process of gradually improving measurements, vigorous disagreements, improving understanding and comparing results from entirely different methods to hone in on the truth.
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The telescopic measurements need to be tested with other measurements, from Earth and at the surface of Mars, to determine whether it is a real process, whether it is routine, or whether the interpretation is a misunderstanding of the data. A powerful argument against my interpretation is that laboratory measurements do not yet show any process that could be effective enough to make this happen to the extent that the measurements appear to show. Also, we don't have the data (yet) to show whether there is a significant seasonal effect in atmospheric isotope ratios on Mars. There probably is not, because lab measurements show that freezing pure ices of CO2 does not result in significantly changing isotope ratios in the remaining gas. But that could be incorrect in the complex environment of a planet's surface. Many types of rock can only form at the surface, where water dissolves both the minerals and the atmosphere so that they can react with each other to form new compounds that can condense to form new minerals. Examples on Earth include limestones (carbonate minerals) and many iron-bearing minerals. The goal of the Perseverance rover mission on Mars now is to obtain samples of surface rocks in the mouth of an ancient river by drilling into the interior of rocks in the streambed to extract pencils of material. The exterior of these rocks has been weathered by the modern Mars environment, but the interior represents the chemical conditions under which the rock formed. This includes the relative rate at which different chemical reactions happened (a thermometer), what was dissolved in the water (including the atmosphere), and what isotope ratios were present for different elements. It is a tremendously ambitious and complex undertaking, involving many first-time events. Much of what we need to investigate to understand ancient Mars is far beyond the capability of instruments that can be made small, light and efficient enough to fit onto a spacecraft. We need these samples from Mars to be returned to Earth where we can use the great variety of instruments we have here to study them completely.