Sodium battery can survive for 2,000 hours by adding Low-cost additive
Sodium-ion batteries (SIBs) are emerging as a viable alternative to lithium-ion batteries (LIBs) due to their material sustainability and cost-effectiveness, helping address the high costs, supply limits and environmental concerns associated with lithium. Recent advances in electrode materials (e.g., layered oxides, hard carbon composites, metallic alloys) are greatly improving SIB stability, conductivity, capacity and cycle life. Improvements in both solid-state and liquid electrolytes have likewise enhanced ionic conductivity, capacity retention, thermal stability and safety. Despite their lower energy density, SIBs tolerate wider temperature ranges and carry a significantly lower risk of thermal runaway compared to lithium-based systems, making them attractive for industrial, transportation and large-scale power storage. Continuous progress in materials and cell engineering is narrowing the performance gap between SIBs and LIBs. Meanwhile, nascent battery recycling strategies for SIBs show promise for economic and environmental viability. Overall, SIBs represent a promising option for safer, more accessible and more sustainable energy storage technology.
Researchers at the National University of Singapore have developed a safer solid-state sodium battery using a low-cost additive which improves ion movement and blocks dangerous metal growth inside the battery. The breakthrough targets one of the biggest challenges facing sodium-ion batteries: safety. While sodium is cheaper and far more abundant than lithium, most sodium batteries still rely on flammable liquid electrolytes which can leak or catch fire. Solid polymer electrolytes are considered a safer alternative, but they typically suffer from poor conductivity and unstable contact with sodium metal electrodes. Over time, dendrites, needle-like metal structures, grow inside the battery and eventually trigger short circuits. The continued growth of solar and wind power is reshaping global energy systems, creating an urgent demand for storage technologies which are both durable and affordable. Despite their promise, high-voltage sodium batteries have remained difficult to commercialize due to a fundamental materials challenge: the electrolyte must stabilize both the highly reactive sodium metal anode and the high-voltage cathode, two surfaces which typically require opposite chemical conditions to remain stable. Traditionally, additives which protect one side of the battery tend to damage the other. This trade-off has been a major barrier to developing practical high-voltage sodium batteries.
The NUS team addressed both problems using graphitic carbon nitride, or GCN, a material produced by heating urea at 550 degrees Celsius. The additive was mixed into a polymer electrolyte film made from polyethylene oxide and sodium salt. The researchers said the ultra-thin GCN sheets reorganized the polymer structure, helping sodium ions move more freely while also improving mechanical strength inside the battery. The modified electrolyte more than doubled ionic conductivity at 55 degrees Celsius and significantly improved the sodium-ion transference number from 0.19 to 0.51. The team said nitrogen-rich sites on the GCN surface helped separate sodium ions from their salt pairs, increasing the number of charge-carrying ions available during operation. “What makes our approach powerful is its simplicity,” said Associate Professor Palani Balaya from NUS. “GCN can be made from one of the most widely available chemical precursors in the world and incorporated into a polymer system that is already scalable.” Repeated charging and discharging typically cause uneven sodium buildup on the electrode surface, eventually producing dendrites which pierce the electrolyte and destroy the battery. The additive helped solve this major problem in sodium-metal batteries: dendrite formation. According to the researchers, the GCN-enhanced polymer became three times stronger than the unmodified version, allowing it to physically resist dendrite penetration. It also formed a more stable protective layer on the sodium metal surface, helping guide uniform sodium deposition.
One of the greatest challenges engineers face is providing reliable power for modern devices and systems. Whether in handheld electronics, vehicles, or grid infrastructure, the need for efficient electrical energy storage is paramount. Rechargeable batteries are a common solution, allowing energy to be stored and released on demand. LIBs are currently the most prevalent form of rechargeable energy storage, largely due to lithium’s high gravimetric energy density. LIBs are found in countless applications and have proven reliable. However, there are drawbacks to lithium-based technology. Lithium is a relatively scarce element. In contrast, sodium is the sixth most abundant element on Earth, widely accessible in the form of sodium salts. Integrating sodium into batteries would mitigate raw material scarcity and reduce the cost of energy storage. Additionally, sodium salts are generally less toxic than lithium salts. On the other hand, SIBs have some inherent challenges. One issue is the larger ionic radius of Na+ compared to Li+, which leads to slower electrochemical kinetics in electrodes. SIBs have also been more difficult to stabilize over long cycle counts, and their cells tend to have lower energy density than LIBs of comparable size.
In testing, the standard polymer electrolyte failed within 250 hours at a current density of 0.1 mA cm-2. The modified version operated stably for 1,000 hours under the same conditions and exceeded 2,000 hours at a higher current density of 0.2 mA cm-2 without failure. The team also built all-solid-state sodium battery cells using a sodium vanadium phosphate cathode and a sodium metal anode. At a 0.5C charge-discharge rate, the batteries retained 95% of their capacity after 500 cycles while maintaining a coulombic efficiency of about 99.97%. Researchers additionally demonstrated a pouch-cell version which continued powering an LED even while being folded, unfolded and cut, showing improved safety and mechanical stability. The team said it is now working on sodium batteries which can operate efficiently closer to room temperature while also developing bipolar stacked architectures aimed at increasing energy density. The approach offers a simple, low-cost route to stabilizing both electrodes simultaneously, enabling long-life sodium batteries which operate at voltages comparable to commercial lithium-ion systems. The study focused on how the additive interacts with ions in the electrolyte. The concept could accelerate this transition by narrowing the performance gap between sodium- and lithium-based technologies while maintaining the resource and cost advantages of sodium.
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